|
|
4-methylsalicylate + O2 + NADH + H+ <=> 4-methylcatechol + CO2 + H2O + NAD+
|
1.14.13.1
salicylate 1-monooxygenase
|
–
|
|
BRENDA:
BS375902
KEGG:
R06939
MetaCyc:
RXN-10078
|
|
|
|
CoA + 4-hydroxybenzoate + ATP <=> 4-hydroxybenzoyl-CoA + diphosphate + AMP
|
6.2.1.27
4-hydroxybenzoate---CoA ligase
|
–
|
|
BRENDA:
BR48381
KEGG:
R01300
MetaCyc:
4-HYDROXYBENZOATE--COA-LIGASE-RXN
SABIO-RK:
1515
|
|
|
|
(4S)-4-hydroxy-2-oxopentanoate <=> (2Z)-2-hydroxypenta-2,4-dienoate + H2O
|
4.2.1.80
2-oxopent-4-enoate hydratase
|
–
|
|
BRENDA:
BR48326
MetaCyc:
2-OXOPENT-4-ENOATE-HYDRATASE-RXN
|
|
|
|
2-hydroxymuconate-6-semialdehyde + H2O <=> formate + 2-oxopent-4-enoate
|
3.7.1.9
2-hydroxymuconate-6-semialdehyde hydrolase
|
–
|
|
BRENDA:
BR26140
KEGG:
R02604
|
|
|
|
2-hydroxy-2,4-hexadienedioate <=> 4-oxalocrotonate
|
5.3.2.6
2-hydroxymuconate tautomerase
5.3.2.M1
|
–
–
|
|
BRENDA:
BR50210;
BS419260;
BS419261;
BS419897
KEGG:
R03966
MetaCyc:
RXN-12354;
RXN-8529
SABIO-RK:
3703
|
|
|
|
phenol + O2 + NADPH + H+ <=> catechol + H2O + NADP+
|
1.14.13.7
phenol 2-monooxygenase (NADPH)
1.14.14.20
phenol 2-monooxygenase (FADH2)
|
–
–
|
|
BRENDA:
BR40412
KEGG:
R00815
MetaCyc:
PHENOL-2-MONOOXYGENASE-RXN
|
|
|
|
4-hydroxy-2-oxopentanoate <=> pyruvate + acetaldehyde
|
4.1.2.52
4-hydroxy-2-oxoheptanedioate aldolase
4.1.3.17
4-hydroxy-4-methyl-2-oxoglutarate aldolase
4.1.3.39
4-hydroxy-2-oxovalerate aldolase
4.1.3.43
4-hydroxy-2-oxohexanoate aldolase
|
–
–
–
–
|
|
BRENDA:
BS378393
KEGG:
R00750
SABIO-RK:
1109
|
|
|
|
catechol + O2 <=> 2-hydroxymuconate-6-semialdehyde + H+
|
1.13.11.1
catechol 1,2-dioxygenase
1.13.11.16
3-carboxyethylcatechol 2,3-dioxygenase
1.13.11.2
catechol 2,3-dioxygenase
1.13.11.36
chloridazon-catechol dioxygenase
1.13.11.37
hydroxyquinol 1,2-dioxygenase
1.13.11.39
biphenyl-2,3-diol 1,2-dioxygenase
|
–
–
–
–
–
–
|
|
BRENDA:
BR40485
KEGG:
R00816
MetaCyc:
CATECHOL-23-DIOXYGENASE-RXN
SABIO-RK:
1159
|
|
|
|
H+ + 4-hydroxybenzoate <=> CO2 + phenol
|
4.1.1.103
gamma-resorcylate decarboxylase
4.1.1.61
4-hydroxybenzoate decarboxylase
|
–
–
|
|
BRENDA:
BR322
KEGG:
R01238
MetaCyc:
4-HYDROXYBENZOATE-DECARBOXYLASE-RXN
SABIO-RK:
1461
|
|
|
|
catechol + O2 <=> H+ + cis,cis-muconate
|
1.13.11.1
catechol 1,2-dioxygenase
1.13.11.3
protocatechuate 3,4-dioxygenase
1.13.11.37
hydroxyquinol 1,2-dioxygenase
|
–
–
–
|
|
BRENDA:
BR37023
KEGG:
R00817
MetaCyc:
CATECHOL-12-DIOXYGENASE-RXN
SABIO-RK:
1160
|
|
|
|
Phenyl_phosphate <=> phenol + phosphate
|
3.1.3.1
alkaline phosphatase
3.1.3.2
acid phosphatase
3.1.3.26
4-phytase
3.1.3.48
protein-tyrosine-phosphatase
3.1.3.8
3-phytase
|
–
–
–
–
–
|
|
BRENDA:
BS364550
SABIO-RK:
7186
|
|
|
|
(4S)-(+)-muconolactone <=> 2-(5-oxo-4,5-dihydrofuran-2-yl)acetic_acid
|
5.3.3.4
muconolactone Delta-isomerase
|
–
|
|
BRENDA:
BR2
KEGG:
R06990
MetaCyc:
MUCONOLACTONE-DELTA-ISOMERASE-RXN
|
|
|
|
benzoyl-CoA + oxidized_ferredoxin + H2O <=> 4-hydroxybenzoyl-CoA + reduced_ferredoxin
|
1.1.7.1
4-hydroxybenzoyl-CoA reductase
|
–
|
|
BRENDA:
BR29449
KEGG:
R05316
|
|
|
|
4-nitrophenyl + O2 + NADH <=> catechol + nitrite + NAD+
|
1.14.12.23
nitroarene dioxygenase
|
–
|
|
BRENDA:
BR51354
KEGG:
R07706
MetaCyc:
RXN-3661
|
|
|
|
Phenyl_phosphate + CO2 + H2O <=> H+ + 4-hydroxybenzoate + phosphate
|
4.1.1.61
4-hydroxybenzoate decarboxylase
6.4.1
|
–
–
|
|
BRENDA:
BS1526
KEGG:
R05603
MetaCyc:
PHENYLPCARB-RXN
|
|
|
|
2-hydroxymuconate-6-semialdehyde + H2O + NAD+ <=> 2-hydroxy-2,4-hexadienedioate + NADH + H+
|
1.2.1.32
aminomuconate-semialdehyde dehydrogenase
1.2.1.85
2-hydroxymuconate-6-semialdehyde dehydrogenase
|
–
–
|
|
BRENDA:
BR50236;
BS258087;
BS370776
KEGG:
R02762
MetaCyc:
RXN-8527
|
|
|
|
2-oxo-3-hexenedioate <=> 2-oxopent-4-enoate + CO2
|
4.1.1.77
2-oxo-3-hexenedioate decarboxylase
|
–
|
|
BRENDA:
BR338
|
|